I had the same lack of highlighting editing xhtml files which have an xhtml extension.
Based on Syntax highlighting for jsx in .js files?
I now use this bookmarklet
javascript:(function() { application.editor().setOption("mode", "text/xml");
CodeMirror.autoLoadMode(application.editor(), "xml"); })()
https://codemirror.net/doc/manual.html#config documents how to use setOptions, in particular “mode”. For example one could also provide xml mode option, it seems.